|
|
4''-O-methylnorbelladine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (10bS,4aR)-noroxomaritidine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.19.50
noroxomaritidine synthase
|
–
|
| |
MetaCyc:
RXN-18127
|
|
|
|
Maritinamine + acceptor <=> (10bR,4aS)-oxomaritinamine + reduced_acceptor
|
1.1
|
–
|
| |
MetaCyc:
RXN-18129
|
|
|
|
(1S,15R,16S)-4-methoxy-9-azatetracyclo[7.6.1.02,7.012,16]hexadeca-2,4,6,12-tetraene-5,15-diol + O2 + reduced_[NADPH-hemoprotein_reductase] <=> Caranine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.19
|
–
|
| |
MetaCyc:
RXN-18153
|
|
|
|
norbelladine + NADP+ <=> Norcraugsodine + NADPH + H+
|
1.4.1
|
–
|
| |
KEGG:
R11751
MetaCyc:
RXN-18121
|
|
|
|
4''-O-methylnorbelladine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> N-Demethylnarwedine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.19
|
–
|
| |
MetaCyc:
RXN-18123
|
|
|
|
S-adenosyl-L-methionine + Norgalanthamine <=> S-adenosyl-L-homocysteine + galanthamine + H+
|
2.1.1
|
–
|
| |
KEGG:
R08441
MetaCyc:
RXN-18125
|
|
|
|
N-Demethylnarwedine + reduced_acceptor <=> Norgalanthamine + acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18124
|
|
|
|
(4aR,10bS)-Normaritidine + acceptor <=> (10bS,4aR)-noroxomaritidine + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18137
|
|
|
|
(4aR,10bS)-Normaritidine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> crinine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.19
|
–
|
| |
MetaCyc:
RXN-18134
|
|
|
|
Vittatine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> 11-hydroxyvittatine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-18140
|
|
|
|
3,4-Dihydroxybenzaldehyde + tyramine <=> Norcraugsodine + H2O + H+
|
4.3.3
|
–
|
| |
KEGG:
R08436
MetaCyc:
RXN-18120
|
|
|
|
H+ + L-tyrosine <=> CO2 + tyramine
|
4.1.1.25
tyrosine decarboxylase
4.1.1.28
aromatic-L-amino-acid decarboxylase
|
–
–
|
| |
BRENDA:
BR286
KEGG:
R00736
MetaCyc:
TYROSINE-DECARBOXYLASE-RXN
SABIO-RK:
1099
|
|
|
|
(-)-8-Demethylmaritidine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> Vittatine + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.19
|
–
|
| |
MetaCyc:
RXN-18136
|
|
|
|
(10bR,4aS)-oxomaritinamine + NADP+ <=> (4aS,10bR)-8-hydroxy-9-methoxy-4,4a-dihydro-3H,6H-5,10b-ethanophenanthridin-3-one + NADPH + H+
|
1.3.1
|
–
|
| |
MetaCyc:
RXN-18138
|
|
|
|
4-hydroxybenzaldehyde + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 3,4-Dihydroxybenzaldehyde + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.1
unspecific monooxygenase
|
–
|
| |
MetaCyc:
RXN-8872
|
|
|
|
S-adenosyl-L-methionine + 11-hydroxyvittatine <=> S-adenosyl-L-homocysteine + (+)-haemanthamine + H+
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-18141
|
|
|
|
Noroxopluviine + reduced_acceptor <=> (1S,15R,16S)-4-methoxy-9-azatetracyclo[7.6.1.02,7.012,16]hexadeca-2,4,6,12-tetraene-5,15-diol + acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18135
|
|
|
|
Caranine + O2 + NADPH + H+ <=> lycorine + H2O + NADP+
|
1.14.13
|
–
|
| |
MetaCyc:
RXN-18152
|
|
|
|
S-adenosyl-L-methionine + norbelladine <=> 4''-O-methylnorbelladine + S-adenosyl-L-homocysteine + H+
|
2.1.1.336
norbelladine O-methyltransferase
|
–
|
| |
BRENDA:
BR51861
KEGG:
R08437
MetaCyc:
RXN-18122
|
|
|
|
4''-O-methylnorbelladine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> Noroxopluviine + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.19
|
–
|
| |
MetaCyc:
RXN-18128
|
|
|
|
(10bS,4aR)-oxomaritinamine + NADP+ <=> (10bS,4aR)-noroxomaritidine + NADPH + H+
|
1.3.1
|
–
|
| |
MetaCyc:
RXN-18126
|
|
|
|
Elwesine + acceptor <=> (10bS,4aR)-oxomaritinamine + reduced_acceptor
|
1.1
|
–
|
| |
MetaCyc:
RXN-18132
|
|
|
|
p-coumaric_acid + H2O <=> 4-hydroxybenzaldehyde + acetate
|
3.7.1
|
–
|
| |
MetaCyc:
RXN-8871
|
|
|
|
4''-O-methylnorbelladine + O2 + reduced_[NADPH-hemoprotein_reductase] <=> (4aS,10bR)-8-hydroxy-9-methoxy-4,4a-dihydro-3H,6H-5,10b-ethanophenanthridin-3-one + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.19.50
noroxomaritidine synthase
|
–
|
| |
MetaCyc:
RXN-18142
|
|
|
|
(-)-8-Demethylmaritidine + acceptor <=> (4aS,10bR)-8-hydroxy-9-methoxy-4,4a-dihydro-3H,6H-5,10b-ethanophenanthridin-3-one + reduced_acceptor
|
not assigned
|
–
|
| |
MetaCyc:
RXN-18133
|
|
